Rhode Island at VT on 10/12 is a 4 PM kickoff on ACC Network.
UNC at VT on 10/19 is Homecoming, a 3:30 kickoff on RSN.
For those that need a reminder about RSN, it stands for regional sports network. For the ACC, these are games that are sublicensed out to Fox to produce, and then they show up on cable. In most areas, it's on the Fox Sports (insert location here) channel. In the mid-Atlantic region, it's on NBC Sports Washington (formerly Comcast Sports Net), as we don't have a Fox Sports RSN here.
ESPN's website will list the game as being on ACCNX (basically the ESPN3 of ACCN), but it's probably blacked out in most areas, because they think you can watch it on TV.
I'm honestly surprised we still have the RSN games, as I figured that they would be absorbed by ACCN. Usually, it was 1 Raycom game and 2 RSNs, which would cover the three games that ACCN would take. I guess we're waiting for that deal to run out.